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Mathematical Modeling of a Lithium Ion Battery

R. E. White[1], and Long Cai[2]
[1]R.E. White & Associates LLC, Columbia, South Carolina, USA
[2]Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina, USA

The existing lithium ion battery model in COMSOL’s Multiphysics  software is extended to include the thermal effects. The thermal behavior of a lithium ion battery is studied during the galvanostatic discharge process with and without a pulse. The existing lithium ion battery model in COMSOL 3.5a is extended by adding an energy balance and the temperature dependence of properties of ...

Comparison of Darcy's Law, the Brinkman Equation, the Modified Navier-Stokes Equation and the Pure Diffusion Equation in PEM Fuel Cell Modeling

Z. Shi and X. Wang
Oakland University, Rochester, MI, USA

A two dimensional isothermal single phase PEM fuel cell model is developed and implemented in COMSOL Multiphysics, where Darcy's law, the Brinkman equation, the modified Navier-Stokes equation, and the pure diffusion equation are applied separately in porous electrodes. Three values of GDL permeability are investigated. Additionally, the order of the magnitude of each term in the modified N-S ...

Influence of Electrode Kinetics on Lithium-ion Battery Characteristics

H. Machrafi[1,2], S. Cavadias[2]
[1]University of Liège, Thermodynamics of Irreversible Phenomena, Liège, Belgium
[2]University Pierre et Marie Curie, Laboratoire des Procédés Plasma et Traitement de Surface, Paris, France

The purpose of this work is to show whether an important difference in Lithium solid concentration and electrolyte concentration can be observed in a Lithium-ion battery model, when considering either the Butler-Volmer kinetics or the Tafel kinetics for describing the electrode kinetics (including a boundary layer between the electrolyte and the electrode particles). During discharge, the lithium ...

Modeling of Liquid Water Distribution at Cathode Gas Flow Channels in Proton Exchange Membrane Fuel Cell – PEMFC

S. Skoda[1], E. Robalinho[2], A. Paulino[1], E.F. Cunha[1], M. Linardi[1]
[1]Instituto de Pesquisas Energéticas e Nucleares, São Paulo, Brazil
[2]Universidade Nove de Julho, São Paulo, Brazil

The objective of this study is to determine the locations where liquid water accumulates at cathode gas flow channels, and the corresponding operating conditions. In such way it is possible to mitigate slug flow, responsible for channel blockage and hindering the diffusion of reactants to the catalytic sites. The model presented here is a comprehensive PEMFC 3D model, which includes liquid water ...

Modeling of Ammonia-fed Solid Oxide Cells in COMSOL Multiphysics®

D. Cheddie[1]
[1]University of Trinidad and Tobago, Couva, Trinidad and Tobago

This paper presents a 2D model of an intermediate temperature ammonia-fed SOFC (400 – 700 °C) based on the Temkin-Pyzhev model of ammonia decomposition. Phenomenological equations are implemented in COMSOL Multiphysics®. The Dusty Gas Model is used to model species transport in porous media, but a modification of Fick’s Law is used. Results show that intermediate temperatures can alleviate ...

Electrical Behaviour of a Li-ion Polymer Battery

P. Alamar[1], J. Esarte[1]
[1]Fundación CETENA, Navarra, Spain

With a view to estimating electrical characteristics of a Polymer Li-ion Battery during specific charge and discharge conditions, a COMSOL Multiphysics® model has been developed that accounts for electrochemical phenomena inside the device. Cell model has been created using the Li-Ion Battery interface, customizing material properties and electrochemical reactions. The electrochemical parameters ...

Numerical Modeling of the Bistability of Electrolyte Transport in Conical Nanopores

H. White[1], L. Luo[1]
[1]Department of Chemistry, University of Utah, Salt Lake City, UT, USA

A characteristic feature of nanochannels is that surface properties (e.g., electrical charge) play a more significant role in the transport of fluid and electrolyte. Two oppositely directed flows (electroosmotic flow and pressure-driven flow) determine the flow profile at the nanopore orifice as well as electrolyte distribution. Once there are two electrolyte solutions with different ...

Modeling of Supercapacitor

G. Madabattula[1], S. K. Gupta[1]
[1]Department of Chemical Engineering, Indian Institute of Science, Bangalore, Karnataka, India

Low cost high energy density batteries that can be charged and discharged rapidly are required in a number of applications. Tapping energy from renewal resources such as solar, wind and tide requires rapidly generated energy to be first stored and then used round the clock. Storing energy of a moving vehicle as it slows down and recovering it to accelerate the vehicle later can significantly ...

Hierarchical Modeling of Polymer Electrolyte Membrane Fuel Cells

J. Dujc[1], J.O. Schumacher[1]
[1]Zurich University of Applied Sciences (ZHAW), Institute of Computational Physics (ICP), Winterthur, Switzerland

A finite element model of a polymer electrolyte membrane fuel cell (PEMFC) is described in this paper. We divide the PEMFC into two separate and parallel 2D regions which are connected by the 1D regions representing the membrane electrode assembly (MEA). COMSOL Multiphysics® was used as a development tool for hierarchical 1D MEA models. Here we present a 1D model that is based on seven governing ...

Modeling Bioelectrochemical Systems for Waste Water Treatment and Bioenergy Recovery with COMSOL Multiphysics®

T. Oyetunde[1], D. Ofiteru[1], J. Rodriguez[1]
[1]Masdar Institute of Science and Technology, Abu Dhabi, United Arab Emirates

Most conventional wastewater treatment processes are quite energy-intensive. Global wastewater production is increasing due to growth in population, industrialization, and urbanization, creating an urgent need for energy-efficient wastewater treatment technologies. Moreover, waste streams (industrial and domestic) have drawn renewed interest as resources for water, energy, and product recovery. ...

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