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Modellierung von Dünnschichtzellen Thin Layer Flow Cell Modelling

E. Holzbecher[1], J. Fuhrmann[1], R. Halseid[2], and R.J. Behm[2]
[1] WIAS, Numerische Analysis, Berlin
[2] Universität Ulm, Ulm

Two designs for thin layer flow cells were set up at University of Ulm, Germany, in order to identify parameters describing the kinetics of methanol-oxydation – reactions, to be utilized in fuel cells. Computer models for two designs were constructed using COMSOL Multiphysics. Results from the numerical simulations were used to evaluate the different flow cell designs. The aim to ...

Modeling the Effect of Discrete Distributions of Platinum Particles in the PEM Fuel Cell Catalyst Layer

C.F. Cetinbas[1], A.K. Prasad[2], S.G. Advani[1]
[1]Center for Fuel Cell Research, Department of Mechanical Engineering, University of Delaware, Newark, DE, USA
[2]University of Delaware, Newark, DE, USA

In this study, the basic catalyst layer (CL) structure, consisting of carbon-supported Pt particles (C|Pt) and an ionomer binder, is investigated numerically by using COMSOL. The significance of modeling discrete Pt particles on the carbon support is highlighted by comparing the cell performance results to the case in which the Pt is assumed to be distributed uniformly over the carbon support as ...

A Model for Panar Self-breathing Proton Exchange Membrane Fuel Cells in FEMLAB

Ziegler, C., Tranitz, M., Schumacher, J.O.
Fraunhofer Institute for Solar Energy Systems, Freiburg, Germany

A mathematical model of planar self-breathing fuel cells is developed and validated. The geometry of the model is a two-dimensional symmetric element of a planar self-breathing fuel cell. The multicomponent transport of the species is considered as well as the couplings between the transport processes of heat, charge, and mass, and the electrochemical reactions. The cell model is validated ...

Steady-state simulation of mono-valent ion distributions within a nanofluidic channel

W. Booth[1], J. Schiffbauer[1], J. Fernandez[2], K. Kelley[3], A. Timperman[3], and B. Edwards[1]

[1]Physics Department, West Virginia University, Morgantown, WV, USA
[2]Chemical Engineering Department, West Virginia University, Morgantown, WV, USA
[3]Chemistry Department, West Virginia University, Morgantown, WV, USA

The steady-state non-equilibrium distributions of two species of mono-valent ions around a charged nanofluidic channel have been examined. Large reservoirs were placed on either side of the nanoscale channel to simulate bulk concentration of ions in a fluid. Results from COMSOL Multiphysics simulations show that the effect of the potential bias across the nanochannel yields a significant ...

Tertiary Current Distributions on the Wafer in a Plating Cell

L. Tong[1]
[1]Keisoku Engineering System Co., Tokyo, Japan

The tertiary current distributions on the wafer in a plating cell are studied in this work. An acid copper sulfate electrolyte composed of CuSO4/5H2O of 2.4 g/L and H2SO4 of 90 g/L is taken into account for copper deposition on the wafer. The solution of shear-plate agitating fluid dynamics is coupled into the calculation of tertiary current distributions. The obtained distributions of tertiary ...

Modeling Proton Transport in Hydrophobic Polymeric Electrolytes

M. Andrews[1]
[1]Caribbean Industrial Research Institute, Calibration Laboratory, University of the West Indies, St. Augustine, Trinidad and Tobago

The Polymer Electrolyte Membrane fuel cell is one of the most promising green technologies for addressing portable, as well as transportation power needs. However, the science behind the fuel cell, in many regards, is still an enigma, and even more so, with the vast numbers of novel materials created annually; designed to offset issues related to durability, conductivity, cost- effectiveness and ...

A Fully Coupled Three-Dimensional Dynamic Model of Polymeric Membranes for Fuel Cells

P. Alotto[1], M. Guarnieri[1], and F. Moro[1]

[1]Dipartimento di Ingegneria Elettrica, Università di Padova, Padova, Italy

The proton exchange membrane is a key component in the currently widely studied Proton Exchange Membrane Fuel Cells. In this paper a fully coupled three-dimensional dynamic numerical model of the membrane including all the physically relevant phenomena, i.e. ion transport, hydration-dependent conductivity and thermal effects is presented. The highly non-linear model is discretized by means of the ...

A Non-isothermal Modeling of a Polymer Electrolyte Membrane Fuel Cell

H. Shin[1]

[1]Department of Mechanical Engineering, University of Michigan – Ann Arbor, Michigan, USA

Polymer electrolyte membrane (PEM) fuel cells have attracted attention as an alternative power source in various applications such as vehicles, portable supplies, and stationary power systems. A non-isothermal PEM fuel model is developed and simulated by using COMSOL Multiphysics. Although PEM fuel cells have been expected to be extensively used as an alternative power source, there have been ...

FEM Simulation of the Scanning Electrochemical Potential Microscopy (SECPM)

R. Hamou, P. Biedermann, M. Rohwerder, and A. Blumeneau
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany

The present work focuses on modeling a new experimental technique: Scanning Electro-chemical Potential Microscopy (SECPM), which is used to probe the potential profile of the electric double layer (EDL). We used an electrostatic approach to compute the EDL potential measured within the metallic probe. Also, we investigated the effect of the interaction of the electrode/probe double layers on the ...

Study of Hydrogen Release from a Metal Hydride Bed

K. Song[1], and H. Knickle[1]

[1]Department of Chemical Engineering, University of Rhode Island, Kingston Rhode Island, USA

In this paper we present a study of the time dependent analysis of a metal hydride bed (MHB) which provides constant flow to a fuel cell at required power loading and pressure. The hydrogen gas phase pressure, the hydrogen concentration in the metal hydride and the hydrogen desorption rate are consider as key variables in this study. Both the space scale and time scale analysis are performed. ...

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