A. Nyman, M. Behm, and G. Lindbergh
Applied Electrochemistry, School of Chemical Science and Engineering, Royal Institute of Technology Stockholm, Sweden
Modeling of mass transport is an important step in evaluating lithium-ion battery electrolytes and understanding cell performance. For high-power applications, concentration gradients in the electrolyte lead to limiting currents, which limit the power-density of the battery. The model has been used for determining a complete set of transport and thermodynamic properties for LiPF6 dissolved in an ...
K. Song, and H. Knickle
Department of Chemical Engineering, University of Rhode Island, Kingston Rhode Island, USA
In this paper we present a study of the time dependent analysis of a metal hydride bed (MHB) which provides constant flow to a fuel cell at required power loading and pressure. The hydrogen gas phase pressure, the hydrogen concentration in the metal hydride and the hydrogen desorption rate are consider as key variables in this study. Both the space scale and time scale analysis are performed. ...
Electrochemical etching of silicon (anodization) is a process that can be used for etching of forms of nearly arbitrary shapes. The difficulty of applying the process for mass production is in the many parameters influencing the process, such as electrolyte concentration and temperature, silicon substrate doping and type, and so on. COMSOL as an FEM simulation tool is very suitable for ...
Renewable Energy RD Center, Chung-Hsin Electric & Machinery, Taiwan
Proton exchange membrane fuel cells (PEMFCs) were investigated using COMSOL Multiphysics with the AC/DC Module and Chemical Engineering Module. Simulation may be used to increase the performance while decreasing the cost of the catalyst later (CL). Experimental validation of single and multi-layer CL was performed for varied PBI electrolyte content. The validated model was used to investigate the ...
Yang, X.1, Zhang, G.1, 2, 3
1 Micro/Nano Bioengineering Laboratory, Department of Biological and Agricultural Engineering
2 Nanoscale Science and Engineering Center
3 Faculty of Engineering, The University of Georgia, Athens, GA 30602, USA
Diffusion controlled redox cycling behavior at nanoscale interdigitated electrodes (IDEs) was simulated using FEMLAB. Cyclic voltammograms were obtained for IDEs with various sizes and spacing, and current collection efficiency and cycling number were calculated. We found that as the size of the IDEs decreased, the shape of the voltammogram changed from a peak-shaped curve to a sigmoidal ...
Department of Mechanical Engineering, University of Michigan – Ann Arbor, Michigan, USA
Polymer electrolyte membrane (PEM) fuel cells have attracted attention as an alternative power source in various applications such as vehicles, portable supplies, and stationary power systems. A non-isothermal PEM fuel model is developed and simulated by using COMSOL Multiphysics. Although PEM fuel cells have been expected to be extensively used as an alternative power source, there have been ...
E. M. Fontes
Catella Generics AB
Computational mathematical modeling has allowed scientists and engineers to perform better, faster, and more economical virtual experiments. Through mathematical modeling, an application expert can simulate performance characteristics during different operating conditions and thereby accelerate the pace of understanding new electrochemical system in relation to specific application ...
N. Godino1, F. J. del Campo2, and F. X. Muñoz1
1Instituto de Microelectrónica de Barcelona, IMB-CNM-CSIC, Barcelona, Spain
2Institut de Biotecnologia i Biomedicina "Vicent Pallar Palasi", Universitat Autónoma de Barcelona, Barcelona, Spain.
Microfluidics enables the miniaturization and integration of sensors into advanced analytical devices. Electrochemical detection is currently one of the preferential techniques of use in microfluidic devices due to its sensitivity, low cost and compatibility with new microfabrication techniques. In this work, we first model the electrochemical response of a set of microband electrodes placed ...
E. Amores, J. Rodriguez Ruiz, C. Merino Rodríguez, and P. García Escribano
Centro Nacional del Hidrógeno
The production of hydrogen from renewable energy surplus is seen as a key strategy for energy storage. Centro Nacional del Hidrógeno works actively in this direction by considering a strategic line in order to achieve a sustainable energy future. Alkaline electrolysis is the main industrial way of obtaining hydrogen by electrolysis. However, commercial alkaline electrolyzers are designed for ...
F. Daouda, J. Hamelin, P. Benard, S. Kumar Natarajan 
Insitut de recherche sur l'hydrogène, Université du Québec à Trois-Rivières, Trois-Rivières, Québec, Canada
We present a novel multi-layered electrode fabrication technique for polymer electrolyte membrane fuel cells (PEMFCs). This method consists of alternate layers of Pt deposition (0.05 mg/cm²) by sputtering on the painted multi-walled carbon-Nafion layer (CNL) with larger concentration of catalyst particles closer to the membrane. Parametric models were developed and validated by experimental ...